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Published in

American Society of Mechanical Engineers, Journal of Engineering for Gas Turbines and Power, 1(136), p. 011502

DOI: 10.1115/1.4025248

Volume 1B: Combustion, Fuels and Emissions

DOI: 10.1115/gt2013-95156

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Numerical study on the effect of real syngas compositions on ignition delay times and laminar flame speeds at gas turbine conditions.

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Depending on the feedstock and the production method, the composition of syngas can include (in addition to H-2 and CO) small hydrocarbons, diluents (CO2, water, and N-2), and impurities (H2S, NH3, NOx, etc.). Despite this fact, most of the studies on syngas combustion do not include hydrocarbons or impurities and in some cases not even diluents in the fuel mixture composition. Hence, studies with realistic syngas composition are necessary to help in designing gas turbines. The aim of this work was to investigate numerically the effect of the variation in the syngas composition on some fundamental combustion properties of premixed systems such as laminar flame speed and ignition delay time at realistic engine operating conditions. Several pressures, temperatures, and equivalence ratios were investigated for the ignition delay times, namely 1, 10, and 35 atm, 900-1400 K, and phi-0.5 and 1.0. For laminar flame speed, temperatures of 300 and 500 K were studied at pressures of 1 atm and 15 atm. Results showed that the addition of hydrocarbons generally reduces the reactivity of the mixture (longer ignition delay time, slower flame speed) due to chemical kinetic effects. The amplitude of this effect is, however, dependent on the nature and concentration of the hydrocarbon as well as the initial condition (pressure, temperature, and equivalence ratio).