Elsevier, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, (95), p. 213-217
DOI: 10.1016/j.saa.2012.04.101
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TiO(2) and Mn-doped TiO(2) (1%, 3% and 5%) nanoparticles (NPs) were synthesized by a sol-hydrothermal method for surface-enhanced Raman spectroscopy study. When using the 4-mercaptobenzoic acid (4-MBA) as the probing molecule, optimum SERS signals were observed on the Mn-TiO(2) (3%) samples. On the 3% Mn doped TiO(2) substrate, 4-MBA molecules exhibit a higher SERS intensity by a factor of six as compared with the native enhancement of 4-MBA adsorbed on pure TiO(2) NPs. The possible mechanism for the phenomena is also discussed. This study opens up a new dimension for the family of SERS substrates.