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Wiley, International Journal of Chemical Kinetics, 1(25), p. 1-8, 1993

DOI: 10.1002/kin.550250102

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Nitrenium ions in N-chloro-?-amino acids decomposition?

Journal article published in 1993 by X. L. Armesto, M. Canle L. ORCID, M. Losada, J. A. Santaballa
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

This article deals with the kinetics of decomposition of four isomers: NCl-(L)-2-Aminohexanoic acid, NCl-(L)-Leucine, NCl-(L)-Isoleucine, and NCl-(L)-tert-Leucine, in mild acid and basic aqueous solution. An alternative mechanism for this process which takes place through a nitrenium-like ion transition state is proposed. This mechanism is in consonance with the experimental data and with those available from the literature. © 1993 John Wiley & Sons, Inc.