Published in

Elsevier, Journal of Alloys and Compounds, 18(509), p. 5453-5459, 2011

DOI: 10.1016/j.jallcom.2011.02.096

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Hydrogen absorption and 57Fe Mössbauer effect in UFeGe

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Hydrogenation of UFeGe transforms the monoclinic type of structure into the orthorhombic (TiNiSi-type) and subsequently to the hexagonal (ZrBeSi-type) structure. It does not induce magnetic order, however magnetic susceptibility is enhanced. The Sommerfeld coefficient γ increases from 12mJ/molK2 in UFeGe to 36mJ/molK2 in UFeGeH1.7–1.8 (β-hydride). The observed variations of electronic properties are mainly due to the modified geometry of the lattice, characterized by enhanced inter-uranium spacing, and reduced 5f–3d hybridization in the hydrides.