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Wiley, Angewandte Chemie International Edition, 3(46), p. 377-380, 2007

DOI: 10.1002/anie.200603414

Wiley, Angewandte Chemie, 3(119), p. 381-384, 2007

DOI: 10.1002/ange.200603414

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[Mn(tmc)(O2)]+: A Side-On Peroxido Manganese(III) Complex Bearing a Non-Heme Ligand

Journal article published in 2007 by Mi Sook Seo, Ja Young Kim, Jamespandi Annaraj, Youngmee Kim, Yong-Min Lee, Sung-Jin Kim, Jinheung Kim, Wonwoo Nam ORCID
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This paper is available in a repository.

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Abstract

(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.