Elsevier, Electrochemistry Communications, (34), p. 235-238
DOI: 10.1016/j.elecom.2013.06.023
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The electrocatalytic properties of vicinal Ag(11n) surfaces for the hydrogen evolution reaction are investigated. An analysis of the reactivity as a function of the step density is performed. The rate constants for Volmer and Heyrovsky steps are evaluated from potentiostatic transients. A correlation between the anisotropy of hydrogen adsorption energy for different sites with the non-linear dependence on the step density is established.