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EDP Sciences, The European Physical Journal Applied Physics, 2(56), p. 24010

DOI: 10.1051/epjap/2011110172

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Ternary association of H+ion with H2at 11 K, experimental study

Journal article published in 2011 by I. Zymak, P. Jusko, Š. Roučka ORCID, R. Plašil, P. Rubovič, D. Gerlich, J. Glosík
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The rate coefficient of the ternary association reaction has been measured at a temperature of 11 K using a 22-pole ion trap. The measurements were made over the density range of 0.5-10 × 1013 cm-3 using normal hydrogen (with 1/4 p-H2 and 3/4 o-H2). We measured an apparent binary reaction rate coefficient and from the obtained linear dependence on the hydrogen density we calculated the ternary reaction rate coefficient k3 = (3 ± 1) × 10-29 cm6 s-1. From the measured data we can deduce that there exists very slow radiative association with the rate coefficient of the order of kr ≲ 3 × 10-16 cm3 s-1 at 11 K.