American Physical Society, Physical Review Letters, 1(100)
DOI: 10.1103/physrevlett.100.015702
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We present the first derivation of the phase field equations using a coarse-graining procedure on a microscopic master equation. The procedure leads to a mesoscopic nonlinear Fokker-Planck equation equivalent to a Cahn-Hilliard equation supplemented with a noise, but with specific prescriptions for the mobilities and the noise term. All the ingredients (chemical potentials, mobilities, stiffness coefficient) depend on the coarse-graining size. Finally, we show the ability of the phase field equations to describe a precipitation kinetics involving a nucleation and growth mechanism.