Published in

American Institute of Physics, The Journal of Chemical Physics, 20(126), p. 204510

DOI: 10.1063/1.2734974

Links

Tools

Export citation

Search in Google Scholar

Thermally activated delayed fluorescence as a cycling process between excited singlet and triplet states: Application to the fullerenes

Journal article published in 2007 by Carlos Baleizão ORCID, Mário N. Berberan Santos ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Orange circle
Published version: archiving restricted
Data provided by SHERPA/RoMEO

Abstract

In efficient thermally activated delayed fluorescence (TADF) the excited chromophore alternates randomly between the singlet and triplet manifolds a large number of times before emission occurs. In this work, the average number of cycles n is obtained and is shown to have a simple experimental meaning: n+1 is the intensification factor of the prompt fluorescence intensity, owing to the occurrence of TADF. A new method of data analysis for the determination of the quantum yield of triplet formation, combining steady-state and time-resolved data in a single plot, is also presented. Application of the theoretical results to the TADF of [70]fullerenes shows a general good agreement between different methods of fluorescence analysis and allows the determination of several photophysical parameters.