Dissemin is shutting down on January 1st, 2025

Published in

The Electrochemical Society, Journal of The Electrochemical Society, 11(152), p. B448

DOI: 10.1149/1.2041867

Links

Tools

Export citation

Search in Google Scholar

Corrosion of Aluminum Current Collectors in Lithium-Ion Batteries with Electrolytes Containing LiPF[sub 6]

Journal article published in 2005 by Xueyuan Zhang, Bryon Winget, Marca Doeff ORCID, James W. Evans, Thomas M. Devine
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Aluminum current collectors for cathodes in 61 life-tested lithium-ion batteries were microscopically examined for evidence of corrosion. In addition, galvanostatic anodic polarization tests were conducted in LiPF 6-containing battery electrolytes on samples of bare aluminum, of aluminum coated with a LiFePO 4 cathode, and of aluminum affixed with polyethylene crevices. The results indicate that aluminum current collectors are susceptible to corrosion, which most likely occurs as underdeposit corrosion at pores in the cathode.