Published in

American Chemical Society, Inorganic Chemistry, 15(47), p. 6590-6592, 2008

DOI: 10.1021/ic800946v

Links

Tools

Export citation

Search in Google Scholar

A 2D Coordination Polymer with Canted Ferromagnetism Constructed from Ferromagnetic [NiIICoII] Nodes

Journal article published in 2008 by Diana G. Branzea, Lorenzo Sorace ORCID, Catalin Maxim, Marius Andruh, Andrea Caneschi ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

A bimetallic coordination polymer, infinity (2)[{LNi (II)Co (II)}(dca) 2], has been constructed from heterobinuclear [Ni (II)Co (II)] nodes and dicyanamido spacers [L (2-) is the dianion of the Schiff base resulting from the 2:1 condensation of 3-methoxysalicyladehyde with 1,3-propanediamine; L (2-) = N, N'-propylenebis(3-methoxysalycilideneiminato)]. The intranode Co (II)-Ni (II) interaction was found to be ferromagnetic because of the orthogonality of the magnetic orbitals. Below 12 K, the onset of the canted ferromagnetic ordering is observed.