Published in
Elsevier, Mendeleev Communications, 5(25), p. 367-369
DOI: 10.1016/j.mencom.2015.09.017
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Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts
Journal article published in 2015 by
Pavel V. Markov,
Igor S. Mashkovsky,
Olga V. Turova,
Aleksandr K. Khudorozhkov,
Valery I. Bukhtiyarov 
,
Aleksandr Y.-U. Stakheev
,
Aleksandr Y.-U. Stakheev
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Abstract
The selectivity in liquid phase semi-hydrogenation of diphenylacetylene (DPA) to cis-stilbene is remarkably improved by increasing Pd particle size due to different structure sensitivity of alkyne and alkene hydrogenation steps.