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American Chemical Society, ACS Nano, 6(9), p. 6297-6304, 2015

DOI: 10.1021/acsnano.5b01794

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Tuning Localized Surface Plasmon Resonance in Scanning Near-Field Optical Microscopy Probes

This paper is available in a repository.
This paper is available in a repository.

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Abstract

A reproducible route for tuning localized surface plasmon resonance in scattering type near-field optical microscopy probes is presented. The method is based on the production of a focused-ion-beam milled single groove near the apex of electrochemically etched gold tips. Electron energy-loss spectroscopy and scanning transmission electron microscopy are employed to obtain highly-spatially and spectroscopically resolved maps of the milled probes, revealing localized surface plasmon resonance at visible and near-infrared wavelengths. By changing the distance L between the groove and the probe apex, the localized surface plasmon resonance energy can be fine-tuned at a desired absorption channel. Tip-enhanced Raman spectroscopy is applied as a test platform, and the results prove the reliability of the method to produce efficient scattering type near-field optical microscopy probes.