The CaSO4:Eu powder composites with and without silver nanoparticles (NP) with selected grain size were analysed by thermoluminescence (TL), photoluminescence (PL) and time-resolved spectroscopy. Both Eu2+ and Eu3+ species are present. The former was identified by the emission around 380 nm and the latter by its typical 5D0-7FJ transitions and two sites were identified. The addition of silver as nanoparticles enhances the TL signal (240 ºC), which is adequate for dosimetry, and has quenching effect on the PL properties, because the most intense luminescence comes from the sample without silver and the lifetimes of the ionic species are not sensitive to the presence of Ag(NP). ; INCT-INAMI ; CNPq ; FAPESP