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Wiley, European Journal of Inorganic Chemistry, 32(2015), p. 5314-5317, 2015

DOI: 10.1002/ejic.201500930

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Mixed-Valent {Mn14} Single-Molecule Magnet Based on Pyridine-2-amidoxime: Mixed-Valent {Mn14} SMM Based on Pyridine-2-amidoxime

Journal article published in 2015 by Xiang Jiang, Guang-Yu An, Cai-Ming Liu ORCID, Hui-Zhong Kou
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This paper is available in a repository.

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Abstract

A new mixed-valent {Mn14} cluster based on pyridine-2-amidoxime (H2pyaox), [MnIV2MnIII10MnII2(μ3-O)8(Hpyaox)14(pyaox)2(N3)2](ClO4)4(OH)2·2MeOH·23H2O (1), has been synthesized and characterized. Magnetic susceptibility studies show that complex 1 displays an S = 6 spin ground state and slow magnetic relaxation.