Surface‐Initiated Polymerization on Self‐Assembled Monolayers: Effect of Reaction Conditions
Journal article published in 2004 by
Ursula Schmelmer,
Anne Paul,
Alexander Küller,
Rainer Jordan 
,
Armin Gölzhäuser ,
Michael Grunze,
Abraham Ulman
,
Armin Gölzhäuser ,
Michael Grunze,
Abraham Ulman
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Abstract
Self-assembled monolayers of 4'-nitro-4-mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface-bond asymmetric azo initiator for the surface-initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.