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Wiley-VCH Verlag, ChemInform, 50(36), 2005

DOI: 10.1002/chin.200550216

Elsevier, Solid State Sciences, 10(7), p. 1280-1288

DOI: 10.1016/j.solidstatesciences.2005.06.001

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Mixed crystalline precursor complexes of the type [Ba(C2H6O2)4][Ti1−xSnx(C2H4O2)3] () for BaTi1−xSnxO3 ceramics: Synthesis, structure and calcination

Journal article published in 2005 by Roberto Koeferstein, Roberto Köferstein ORCID, Lothar Jaeger, Lothar Jäger, Volker Lorenz, Hans-Peter Abicht, Jörg Woltersdorf, Eckhard Pippel, Helmar Goerls, Helmar Görls
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This paper is available in a repository.

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Abstract

The synthesis of [Ba(C2H6O2)(4)][Ti(C2H4O2)(3)], its crystal structure and thermal decomposition is described. This 1,2-ethanediolato complex forms with the isotypic tin compound [Ba(C2H6O2)(4)][Sn(C2H4O2)(3)] solid solutions [Ba(C2H6O2)(4)][Ti1-xSnx(C2H4O2)(3)] in any ratio. Corresponding mixed crystalline samples are suitable precursor complexes for BaTi1-xSnxO3 ceramics with the feature of a heavy element distribution in molecular scale matching the element distribution of the final ceramics. (c) 2005 Elsevier SAS. All rights reserved.