Dissemin is shutting down on January 1st, 2025

Published in

American Chemical Society, Journal of Physical Chemistry C, 19(114), p. 8741-8748, 2010

DOI: 10.1021/jp100456p

Links

Tools

Export citation

Search in Google Scholar

Surface-Stress-Driven Lattice Contraction Effects on the Extinction Spectra of Ultrasmall Silver Nanowires

Journal article published in 2010 by Harold S. Park ORCID, Xiaohu Qian
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

Full text: Unavailable

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

We utilize numerical simulations based on the discrete dipole approximation to study the effects of surface-stress-driven lattice contraction on the extinction spectra of silver nanowires with a square cross section of length 2 nm. The novel finding of the present work is the determination that the blue shift that is induced in the silver nanowires due to surface-stress-driven lattice contraction increases with an increase in the nanowire aspect ratio; the blue shift in the longitudinal plasmon resonance wavelength reaches 20 nm in air and 30 nm in water when the nanowire aspect ratio increases to six. Furthermore, we have delineated the lattice contraction effects on the relative contributions of the free (conduction) electrons and the ionic core (bound) electrons to the observed blue shift; specifically, due to the increasingly free electron optical response of the nanowires with increasing aspect ratio, the blue shift due to the contraction-driven increase in the free electron density is found to dominate the red shift due to the increase in the core electron density for larger nanowire aspect ratios. The results collectively indicate that surface-stress-driven lattice contraction plays an important role in blue shifting the longitudinal plasmon resonance wavelength for ultrasmall silver nanowires.