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Springer Verlag, Journal of the Korean Physical Society, 7(66), p. 1077-1081

DOI: 10.3938/jkps.66.1077

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Ergodicity and nonergodicity in La-doped Bi1/2(Na0.82K0.18)1/2TiO3 relaxors

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This paper is available in a repository.

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Abstract

The phase transition of La-doped [Bi1/2(Na0.82K0.18)1/2]TiO3 (BNKT) ceramics was investigated by using high-temperature X-ray diffraction and temperature-dependent dielectric measurements. Undoped BNKT was found to be a nonergodic relaxor, which was evidenced by the presence of a depolarization temperature below which polar nanoregions were frozen. However, La-doped BNKT ceramics are believed to be composites consisting of ergodic and nonergodic relaxors. The results suggest that a nonergodic relaxor with tetragonal symmetry might be distributed in an ergodic relaxor matrix with pseudocubic symmetry.