Published in
Elsevier, Journal of Organometallic Chemistry, (741-742), p. 40-46
DOI: 10.1016/j.jorganchem.2013.05.021
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Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
Journal article published in 2013 by
Kai Ning Wong,
Garvin Kar Hang Mak,
Kar Hang Garvin Mak,
Wai Yip Fan,
Venugopal Shanmugham Sridevi,
Weng Kee Leong 
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Abstract
Reaction of the dimeric species [Cp*IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in C–C bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally. ; MOE (Min. of Education, S’pore)