Binder-free NiO-CoO hybrid electrodes were directly grown on the nickel foam by electrodeposition and subsequently annealing in 5% H2/ 95% N2 gas at 300℃. Crystal structure, elemental analysis, surface morphology and chemical compositions of the composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) equipped with an energy dispersive X-ray analysis system. The hydrogenated NiO-CoO hybrid electrodes were evaluated as electrode for supercapacitors which demonstrated promising electrochemical performance with high specific capacitance, excellent rate capability, and stable cycling.