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American Chemical Society, Journal of the American Chemical Society, 17(134), p. 7254-7257, 2012

DOI: 10.1021/ja301462e

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Acyclic Cucurbit[n]uril Molecular Containers Selectively Solubilize Single-Walled Carbon Nanotubes in Water

Journal article published in 2012 by Cai Shen, Da, Da Ma, Brendan Meany, Lyle Isaacs ORCID, YuHuang Wang
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Making single-walled carbon nanotubes (SWNTs) soluble in water is a challenging first step to use their remarkable electronic and optical properties in a variety of applications. We report that acyclic cucurbit[n]uril molecular containers 1 and 2 selectively solubilize small-diameter and low chiral angle SWNTs. The selectivity is tunable by increasing the concentration of the molecular containers or by adjusting the ionic strength of the solution. Even at a concentration 1000 times lower than typically required for surfactants, the molecular containers render SWNTs soluble in water. Molecular mechanics simulations suggest that these C-shaped acyclic molecules complex the SWNTs such that a large portion of nanotube sidewalls are exposed to the external environment. These "naked" nanotubes fluoresce upon patching the exposed surface with sodium dodecylbenzene sulfonate.