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American Chemical Society, Organometallics, 9(26), p. 2456-2460, 2007

DOI: 10.1021/om070062z

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Bimetallic (Iron or Cobalt) Complexes Bearing 2-Methyl-2,4-bis(6-iminopyridin-2-yl)-1H-1,5-benzodiazepines for Ethylene Reactivity

Journal article published in 2007 by Shu Zhang, Igor Vystorop, Zhenghua Tang, Wen-Hua Sun ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A series of bimetallic (ferrous and cobaltous) complexes ligated by 3,3-dihydro-2-methyl-2,4-bis(6-iminopyridin-2-yl)-1H-1,5-benzodiazepines were synthesized and evaluated as catalysts for ethylene oligomerization and polymerization with high activity and α-olefin selectivity in the presence of modified methylaluminoxane (MMAO).