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American Chemical Society, Journal of the American Chemical Society, 24(134), p. 9860-9863, 2012

DOI: 10.1021/ja302623w

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Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better Than Phenyls?

Journal article published in 2012 by Omar K. Farha, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin O'Neill, Amy A. Sarjeant, SonBinh T. Nguyen ORCID, Randall Q. Snurr ORCID, Joseph T. Hupp
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.