Elsevier, Journal of Molecular Catalysis A: Chemical, 1-2(305), p. 178-182
DOI: 10.1016/j.molcata.2009.01.002
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The aqua-soluble multinuclear copper(II) compounds [Cu2(μ-H2tea)2{μ3-Na2(H2O)4}(μ6-pma)]n·10nH2O (1) and [O⊂Cu4(tea)4(BOH)4][BF4]2 (2) (H3tea=triethanolamine, H4pma=pyromellitic acid) have been applied as efficient catalysts for the mild, selective and clean oxidation of benzyl alcohols to benzaldehydes, which proceeds in sole water as solvent at 50°C, under atmospheric pressure of air (or O2) as oxidant, and is mediated by TEMPO radical. Molar yields of benzaldehydes (based on alcohol) up to 99% have been achieved (with a high selectivity). Attractive features of these catalytic systems include the use of organic-solvent-free reaction medium, air or dioxygen as oxidant, and aqua-soluble copper catalysts that are readily available by self-assembly.