American Institute of Physics, Applied Physics Letters, 6(90), p. 063114
DOI: 10.1063/1.2457525
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The authors describe a chemical patterning technique, ``microcontact insertion printing,'' that utilizes conventional microcontact printing to pattern isolated molecules diluted within a preexisting self-assembled monolayer. By modifying the preexisting monolayer quality, the stamping duration, and/or the concentration of the patterned molecule, they can influence the extent of molecular exchange and precisely control the molecular composition of patterned self-assembled monolayers. This simple methodology can be used to fabricate complex patterns via multiple stamping steps and has applications ranging from bioselective surfaces to molecular-scale electronic components.