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American Geophysical Union, Geochemistry, Geophysics, Geosystems, 4(14), p. 1053-1068, 2013

DOI: 10.1029/2012gc004296

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A core-top study of dissolution effect on B/Ca inGlobigerinoides sacculiferfrom the tropical Atlantic: Potential bias for paleo-reconstruction of seawater carbonate chemistry

Journal article published in 2013 by R. Coadic, F. Bassinot, D. Dissard ORCID, E. Douville, M. Greaves, E. Michel
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

It has been recently shown that B/Ca in planktonic foraminiferal calcite can be used as a proxy for seawater pH. Based on the study of surface sediments (multi-cores) retrieved along a depth transect on the Sierra Leone Rise (Eastern Equatorial Atlantic), we document the decrease of B/Ca and Mg/Ca of Globigerinoides sacculifer shells with increasing water depth and dissolution. This effect of dissolution on B/Ca may potentially represent a severe bias for paleo-pH reconstructions using this species. Samples of G. sacculifer were analyzed independently at two laboratories for B/Ca and Mg/Ca. Both sets of results show a systematic decrease of B/Ca and Mg/Ca along the depth transect, with an overall loss of similar to 14 mu mol/mol (similar to 15%) for B/Ca and of similar to 0.7mmol/mol (similar to 21%) for Mg/Ca between the shallowest (2640m) and the deepest (4950m) sites. Because of this dissolution effect, surface water pH reconstructed from B/Ca of G. sacculifer decreases by similar to 0.11 units between the shallowest site and the deepest site, a magnitude similar to the expected glacial/interglacial surface water pH changes