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Wiley, Angewandte Chemie International Edition, 45(51), p. 11350-11353, 2012

DOI: 10.1002/anie.201205057

Wiley, Angewandte Chemie, 45(124), p. 11512-11515

DOI: 10.1002/ange.201205057

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Mechanism of Formation of Palladium Nanoparticles: Lewis Base Assisted, Low-Temperature Preparation of Monodisperse Nanoparticles

Journal article published in 2012 by Renee W. Y. Man, Adam R. C. Brown, Michael O. Wolf ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Small and cool: The mechanism of formation of amine-capped Pd nanoparticles from [Pd(acac)(2) ] (acac=acetylacetonate) is elucidated, and shown to involve Pd-amido and Pd-hydride intermediates. The addition of a Lewis base results in a significant reduction in the temperature at which highly monodisperse nanoparticles are isolated.