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American Chemical Society, Organic Letters, 8(7), p. 1617-1619, 2005

DOI: 10.1021/ol050306g

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A Concise Route to the Azaspirodecane Moiety of Halichlorine and Structurally Related Alkaloids

Journal article published in 2005 by Andrea L. de Sousa, Ronaldo A. Pilli ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

[reaction: see text] A tandem Michael addition-enolate alkylation followed by Dieckmann cyclization and Beckmann rearrangement provided the corresponding [5.4.0] azaspirobicyclodecane, a key intermediate in our synthetic route to the marine alkaloid halichlorine (1).