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Wiley, Angewandte Chemie International Edition, 4(48), p. 815-819, 2009

DOI: 10.1002/anie.200803984

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Discrete Supramolecular Donor-Acceptor Complexes

This paper is available in a repository.
This paper is available in a repository.

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Abstract

(Figure Presented) On the ball: Charge transfer occurs readily in tightly interacting complexes formed from π-extended tetrathiafulvalenes, which act as pincerlike receptors, and C60 in a variety of solvents upon photoexcitation (see picture; PET = photoelectron transfer). It should be feasible to construct simple photovoltaic devices from systems based on similar recognition motifs.