Published in

Elsevier, Journal of the European Ceramic Society, 14-15(22), p. 2595-2602

DOI: 10.1016/s0955-2219(02)00121-8

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Microstructure of Y2O3 Doped Al2O3–ZrO2 Eutectics Grown by the Laser Floating Zone Method

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Al2O3–ZrO2 eutectics containing 9 mol% Y2O3 (with respect to zirconia) were produced by directional solidification using the laser floating zone (LFZ) method. The eutectic microstructures were investigated as a function of the growth variables. Using a solidification-axis thermal gradient of 600 °C/mm a homogeneous, colony-free, interpenetrating lamellar microstructure was obtained for growth rates less than 50 mm/h. Higher growth rates produce cellular structures. Colonies grew with the [0001] alumina and the [110] zirconia axis parallel to the growth direction. The uniform lamellar microstructure obtained at low growth rates is stable during thermal treatment at 1500 °C.