Published in

The Journal of Physical Chemistry, 4(95), p. 1850-1858

DOI: 10.1021/j100157a064

Links

Tools

Export citation

Search in Google Scholar

Micelle and gel formation in a poly(ethylene oxide)/poly(propylene oxide)/poly(ethylene oxide) triblock copolymer in water solution: dynamic and static light scattering and oscillatory shear measurements

Journal article published in 1991 by Wyn Brown, Karin Schillen ORCID, Mats Almgren, Soeren Hvidt, Pratap Bahadur
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The properties of aqueous solutions of low molecular weight triblock copolymers of PEO/PPO/PEO have been investigated, mainly by dynamic and static light scattering. At low concentrations (C < 10%) and temperature (< 25-degrees-C) the relaxation time distributions from dynamic light scattering show the coexistence of the monomer (R(H) almost-equal-to 18 angstrom), micelles (R(H) almost-equal-to 80 angstrom), and micellar aggregates in relative proportions which depend critically on temperature and concentration. Micelles are formed at about C = 5% at 25-degrees-C. At 40-degrees-C and above micelles are present at all concentrations used (C > 0.3%). At infinite dilution the hydrodynamic radius of the micelles is approximately constant over the temperature range 15-50-degrees-C. At finite concentrations the apparent micellar radius increases with increasing temperature. The growth into asymmetric particles with increasing concentration is stronger as demonstrated by ultracentrifugation and combining static and dynamic light scattering data. At higher concentrations, a solidlike gel is formed at a well-defined temperature as shown by oscillatory shear measurements. It is characterized by a dynamic correlation length which decreases monotonically with increasing concentration to about 20 angstrom.