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American Chemical Society, Organic Letters, 15(16), p. 3860-3863, 2014

DOI: 10.1021/ol501644c

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Pd-Containing Organopolyoxometalates Derived from Dawson Polyoxometalate [P2W15V3O62](9-): Lewis Acidity and Dual Site Catalysis.

Journal article published in 2014 by Benoît Riflade, David Lachkar, Julie Oble, Joaquim Li, Serge Thorimbert ORCID, Bernold Hasenknopf, Emmanuel Lacôte
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Grafting of a palladium complex to the Dawson vanadotungstate polyanion [P2W15V3O62](9-) via an organic ligand generates a large family of pincer-type hybrid polyoxometalates. The palladium-POM derivatives have dual catalytic properties. Unlike their parent inorganic polyanions, they catalyze allylations while retaining their oxidant character, which leads to single-pot dual site catalysis. This opens a new route for multicatalytic reactions.