Published in
American Chemical Society, Inorganic Chemistry, 10(50), p. 4232-4234, 2011
DOI: 10.1021/ic2003639
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A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior
Journal article published in 2011 by
Humphrey L. C. Feltham,
Rodolphe Clérac,
Annie K. Powell,
Sally Brooker 
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Abstract
3 pages ; International audience ; [CuII3TbIII(LPr)(NO3)2(MeOH)(H2O)2]-(NO3) 3 3H2O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.