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Wiley, Angewandte Chemie, 39(122), p. 7128-7132, 2010

DOI: 10.1002/ange.201001833

Wiley, Angewandte Chemie International Edition, 39(49), p. 6974-6978, 2010

DOI: 10.1002/anie.201001833

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The Hierarchical Self-Assembly of Charge Nanocarriers: A Highly Cooperative Process Promoted by Visible Light

Journal article published in 2010 by Emilie Moulin, Fréderic Niess, Mounir Maaloum, Eric Buhler ORCID, Irina Nyrkova, Nicolas Giuseppone
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Let there be more light: Triarylamine-based building blocks respond to visible-light exposure by the formation of cationic radicals that hierarchically self-assemble into molecular wires, which in turn combine within larger fibers (see picture). The stimuli-responsive supramolecular scaffold, which is created by charge transfer and reversibly broken up by heating, prevents the quenching of holes within the wires.