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American Chemical Society, Inorganic Chemistry, 13(48), p. 5623-5625, 2009

DOI: 10.1021/ic9005218

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Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)−carboxylate complex

Journal article published in 2009 by Artur Motreff, Rosenildo Correa Da Costa, Hassan Allouchi, Mathieu Duttine, Corine Mathonière, Carole Duboc ORCID, Jean-Marc Vincent
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The very fast and efficient water vapor absorption of the dimeric fluorous copper(II)-carboxylate complex [Cu(2)(C(8)F(17)CO(2))(4)(acetone)(2)] (1) leads, in the solid state, to a dramatic decrease of the exchange magnetic coupling between the copper(II) ions and to a drastic change of its powder EPR spectrum.