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Elsevier, Journal of Solid State Chemistry, 8(180), p. 2346-2355

DOI: 10.1016/j.jssc.2007.06.006

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The Chemistry of the Phosphates of Barium and Tetravalent Cations in the 1:1 Stoichiometry

Journal article published in 2007 by Konings Rudy, Gouder Thomas, P. E. Ralson, Karin Popa ORCID, Damien Bregiroux, Rudy J. M. Konings, Aurelian Florin Popa, T. Gelsler, Thorsten Geisler, Raison Philippe, Philippe E. Raison
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Abstract

The chemistry of phosphates of barium and tetravalent cations [BaMIV(PO4)2] is reviewed. Such phosphates crystallise in the C2/m space group for MIV 1/4 Ti, Zr, Hf, Ge, Sn, and Mo, and in the P21/n space group for BaTh(PO4)2. The existence of BaMIV(PO4)2 in which MIV 1/4 Pb, Ce, and U is further evaluated. Several aspects, such as phase transitions in the compounds with yavapaiite structure, solid solutions of BaMIV(PO4)2 compounds and practical applications are briefly discussed. ; JRC.E.4-Nuclear fuels