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Elsevier, Chemical Physics Letters, 1-3(421), p. 242-245

DOI: 10.1016/j.cplett.2005.12.105

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Limits of the PECVD process for single wall carbon nanotubes growth

Journal article published in 2006 by A. Gohier, Tm M. Minea, M. A. Djouadi, A. M. Djouadi, Agnès Granier ORCID, M. Dubosc
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

This Letter explores the capabilities of plasma enhanced chemical vapor deposition to grow vertical oriented single wall, double wall or multi walled carbon nanotubes (CNTs). Our dual process uses high-density low-pressure plasma excited by electron cyclotron resonance using acetylene diluted in ammonia. The early stages of CNTs synthesis have been probed taking advantage of the low growth rate of our process. Two antagonist effects have been shown up: the formation of catalyzed carbon nanotubes against ion assisted bonds breaking. The limits of plasma single wall CNTs growth are discussed and transitory stages have been revealed for the first time.