Dissemin is shutting down on January 1st, 2025

Published in

Elsevier, Chemical Physics Letters, 4-6(391), p. 273-277

DOI: 10.1016/j.cplett.2004.05.020

Links

Tools

Export citation

Search in Google Scholar

A photomagnetic study of three iron(II) compounds containing ligands from the 2,6-di(pyrazol-1-yl)pyridine series

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

A comprehensive study of the photomagnetic behaviour of [Fe(L1)2](BF4)2, [Fe(L2)2](BF4)2 and [Fe(L2)2](ClO4)2 where L1=2,6-di(pyrazol-1-yl)pyridine and L2=2,6-di(pyrazol-1-yl)pyrazine has been carried out. The critical Light Induced Excited Spin State Trapping (LIESST) temperatures (T(LIESST)) of all three compounds are presented. The kinetics of the transition from the metastable high spin state to the low spin state have been investigated and examination of the photomagnetic behaviour under constant irradiation has shown the Light Induced Thermal Hysteresis (LITH) behaviour of the compounds. This work completes the crystallographic data previously published and proves the quantitative photoconversion at low temperature of all these derivatives.