Published in

International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 8(68), p. o2460-o2460, 2012

DOI: 10.1107/s1600536812031625

Links

Tools

Export citation

Search in Google Scholar

1-(2,4-Difluoro­phen­yl)thio­urea

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The asymmetric unit of the title compound, C7H6F2N2S, consists of two independent molecules, with comparable geometries. In one molecule, the thiourea moiety is essentially planar (r.m.s. deviation = 0.014 Å) and it forms a dihedral angle of 78.67 (9)° with the benzene ring. The corresponding r.m.s. deviation and dihedral angle for the other molecule are 0.011 Å and 81.71 (8)°, respectively. In both molecules, one of the F atoms is disordered over two positions with refined site occupancies of 0.572 (3):0.428 (3) and 0.909 (2):0.091 (2), respectively. In the crystal, molecules are linkedviaN—H...S and C—H...F hydrogen bonds into two-dimensional networks parallel to (010).