American Chemical Society, Journal of the American Chemical Society, 21(133), p. 8126-8129, 2011
DOI: 10.1021/ja202156u
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High-field, single-crystal EPR spectroscopy on a tetragonal bisdiselenazolyl ferromagnet has provided evidence for the presence of easy-axis magnetic anisotropy, with the crystallographic c axis as the easy axis and the ab plane as the hard plane. The observation of a zero-field gap in the resonance frequency is interpreted in terms of an anisotropy field several orders of magnitude larger than that observed in light-heteroatom, nonmetallic ferromagnets and comparable (on a per-site basis) to that observed in hexagonal close packed cobalt. The results indicate that large spin-orbit-induced magnetic anisotropies, typically associated with 3d-orbital-based ferromagnets, can also be found in heavy p-block radicals, suggesting that there may be major opportunities for the development of heavy p-block organic magnetic materials.