Published in

American Physical Society, Physical review B, 4(72), 2005

DOI: 10.1103/physrevb.72.045114

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Fine structure in the quadrupolar transition of the HoL3pre-edge observed by lifetime-broadening-suppressed XANES spectroscopy

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

The 2p3d resonant inelastic x-ray-scattering spectra of Ho2O3 are measured under 0.7 eV resolution and analyzed in terms of an equation based on the Kramers-Heisenberg formula. Broadening due to core-hole lifetime (4.26 eV) is completely suppressed to give sharp absorption bands with width of <0.5 eV together with energy position uncertainty ∼0.3 eV. Observed bands are assigned to be well-known 2p→4f quadrupolar transitions that are otherwise buried under lifetime-broadened intense 2p→5d dipole transition. The present work opens up an opportunity to study 4f-5d interactions more accurately.