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American Physical Society, Physical Review Letters, 1(100)

DOI: 10.1103/physrevlett.100.017002

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Superconductivity in the Platinum GermanidesMPt4Ge12(M=Rare−Earthor Alkaline-Earth Metal) with Filled Skutterudite Structure

Journal article published in 2008 by R. Gumeniuk ORCID, W. Schnelle, H. Rosner, M. Nicklas, A. Leithe-Jasper, Y.-U. Grin
This paper is available in a repository.
This paper is available in a repository.

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Abstract

New germanium-platinum compounds with the filled-skutterudite crystal structure were synthesized. The crystal structure and composition were investigated by x-ray diffraction and microprobe analysis. Magnetic susceptibility, specific heat, and electrical resistivity measurements evidence superconductivity in LaPt4Ge12 and PrPt4Ge12 below 8.3 K. The parameters of the normal and superconducting states were established. Strong coupling and a crystal electric field singlet ground state is found for the Pr compound. Electronic structure calculations show a large density of states at the Fermi level. Similar behavior with lower Tc was observed for SrPt4Ge12 and BaPt4Ge12.