Transformation of the [MnII2MnIII2(hmp)6]4+Core into [CoIII2MnII2(hmp)6]4+in the Reaction of the [Mn4(hmp)6(NO3)2(H2O)2] Cluster with [CoX4]2-(X = Cl, Br)

Kushch, Lyudmila A.; Yagubskii, Eduard B.; Simonov, Sergey V.; Shibaeva, Rimma P.; Suturina, Elizaveta A.; Gritsan, Nina P.; Sadakov, Andrei V.; Sulimenkov, Il'ya V.

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Wiley, European Journal of Inorganic Chemistry, 32(2013), p. 5603-5611, 2013

DOI: 10.1002/ejic.201300652

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Transformation of the [MnII2MnIII2(hmp)6]4+Core into [CoIII2MnII2(hmp)6]4+in the Reaction of the [Mn4(hmp)6(NO3)2(H2O)2] Cluster with [CoX4]2-(X = Cl, Br)

Journal article published in 2013 by Lyudmila A. Kushch, Eduard B. Yagubskii, Sergey V. Simonov, Rimma P. Shibaeva, Elizaveta A. Suturina, Nina P. Gritsan

, Andrei V. Sadakov, Il'ya V. Sulimenkov

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Abstract

The reactions of [Mn-4(hmp)(6)(NO3)(2)(H2O)(2)](ClO4)(2) with (Bu4N)(2)[CoX4] (X = Cl, Br) in CH3CN have been studied and the new heterometallic tetranuclear clusters [(Co2Mn2II)-Mn-III(hmp)(6)Cl-2(CH3CN)(2)]Mn(II)Cl(4)3CH(3)CN and [(Co2Mn2II)-Mn-III(hmp)(6)Br-2(CH3CN)(2)]Mn(II)Br(4)4CH(3)CN have been synthesized and characterized by TGA, electrospray ionization mass spectrometry, single-crystal X-ray diffraction, and magnetic measurements. The magnetic properties of the heterometallic clusters were analyzed by DFT and ab initio calculations.

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Transformation of the [MnII2MnIII2(hmp)6]4+Core into [CoIII2MnII2(hmp)6]4+in the Reaction of the [Mn4(hmp)6(NO3)2(H2O)2] Cluster with [CoX4]2-(X = Cl, Br)

Abstract