Complex-oxide superlattices (SLs) with atomic-scale periodicity have dynamical properties that are distinct from thin films of uniform composition. The origins of these properties are closely related to the dynamics of polarization domains and to field-driven changes in the symmetries resulting from interfacial coupling between different components. These dynamics are apparent at timescales from a few nanoseconds to several milliseconds in experiments probing the piezoelectricity of a ferroelectric/dielectric BaTiO 3 (BTO)/CaTiO 3 (CTO) SL using time-resolved x-ray microdiffraction. At the 100 ns timescale, the piezoelectric distortion is approximately ten times smaller than in the millisecond regime. This reduced piezoelectricity at short timescales is not observed in previously studied PbTiO 3 /SrTiO 3 SLs or compositionally uniform ferroelectrics such as tetragonal compositions of Pb(Zr, Ti)O 3 . The unusual behavior of the BTO/CTO SL can be linked to the switching of a nanodomain state into a uniform polarization state or to a field-induced crystallographic symmetry transition. A comparison of the results 5 These authors have contributed equally to this work. 2 with the characteristic timescales of these two dynamical phenomena in other complex oxides with different compositions suggests that the phase transition is a more likely possibility.