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Elsevier, Journal of Photochemistry and Photobiology A: Chemistry, 1-3(104), p. 25-33, 1997

DOI: 10.1016/s1010-6030(96)04575-3

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Gas-phase UV spectroscopy of anthracene, xanthone, pyrene, 1-bromopyrene and 1,2,4-trichlorobenzene at elevated temperatures

Journal article published in 1997 by Andreas Th6ny, A. Th{̈o}ny, Andreas Thony, Michel J. Rossi ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We present quantitative UV-absorption spectra in the wavelength range 200 to 400 nm and the temperature range 150 to 600 °(2 for anthracene, xanthone, pyrene, l-bromopyrene and 1,2,4-trichlorobenzene obtained at I atm of air in a slowly flowing gas mixture. As a general trend, the spectra shift to the red with increasing temperature and decrease in peak intensity thus leading to a loss of the characteristic structure of the spectrum. The absorption integrated over a particular band generally stays constant or slightly decreases with increasing temperature. © 1997 Elsevier Science S.A. (J. Photochem. Photobiol. A: Chemistry, 104 (1997), 25-33).