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American Chemical Society, The Journal of Physical Chemistry A, 45(113), p. 12599-12606, 2009

DOI: 10.1021/jp904862a

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Gas-Phase Energetics of Actinide Oxides: An Assessment of Neutral and Cationic Monoxides and Dioxides from Thorium to Curium

Journal article published in 2009 by Joaquim Marçalo ORCID, John K. Gibson
This paper is available in a repository.
This paper is available in a repository.

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Abstract

An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.