Published in
Elsevier, Journal of Molecular Structure, 1-3(1005), p. 141-143
DOI: 10.1016/j.molstruc.2011.08.039
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Trans-ligand-dependent arrangement (bent or linear) of PtII-bound dialkylcyanamide ligands: Molecular structure of trans-dichloro(dimethylcyanamide)(dimethyl sulfoxide)platinum(II)
Journal article published in 2011 by
Tatyana B. Anisimova,
Nadezhda A. Bokach 
,
Igor O. Fritsky,
Matti Haukka
,
Igor O. Fritsky,
Matti Haukka
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Abstract
The title compound, trans-[PtCl2(NCNMe2)(Me2SO)], is the first example of the structurally characterized PtII species having the nitrile and the sulfoxide ligands in the trans-position to each other. The most significant feature of this structure is the non-linear arrangement of the PtN1C1 fragment providing the rare case of the bent form of the dialkylcyanamide ligand.