Dissemin is shutting down on January 1st, 2025

Published in

The Electrochemical Society, Journal of The Electrochemical Society, 12(154), p. C719

DOI: 10.1149/1.2789292

Links

Tools

Export citation

Search in Google Scholar

Experimental Issues Associated with Measurement of Local Electrochemical Impedance

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

A detailed analysis from both numerical calculations and experimental results is presented for the local electrochemical impedance spectroscopy (LEIS) measurements of a disk electrode, which accounted for the placement of the LEIS probe above the electrode surface. The calculations for an electrode with a local constant phase element behavior were in excellent agreement with experimental observations for a stainless steel electrode in a Na2SO4/NaCl (pH4) electrolyte. Measurement of the local impedance at two positions above the electrode surface allowed estimations of the local interfacial impedance and the local ohmic impedance, which were in excellent agreement with the simulations. The results demonstrate that the local impedance measurement itself cannot be used to estimate the surface area sampled by the LEIS probe. The area sampled must be determined instead by the probe geometry. (c) 2007 The Electrochemical Society.