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American Chemical Society, ACS Nano, 11(6), p. 10076-10081, 2012

DOI: 10.1021/nn303793w

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Molecule-by-Molecule Writing Using a Focused Electron Beam

This paper is available in a repository.
This paper is available in a repository.

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Abstract

The resolution of lithography techniques needs to be extended beyond their current limits to continue the trend of miniaturization and enable new applications. But what is the ultimate spatial resolution? It is known that single atoms can be imaged with a higly focused electron beam. Can single atoms also be written with an electron beam? We verify this with focused electron beam induced deposition (FEBID), a direct-write technique that has the current record for the smallest feature written by (electron) optical lithography. We show that the deposition of an organometallic precursor on graphene can be followed molecule by molecule with FEBID. The results show that mechanisms that are inherent to the process inhibit a further increase in control over the process. Hence, our results present the resolution limit of (electron) optical lithography techniques. The writing of isolated, sub-nm features with nanometer precision can be used for instance for the local modification of graphene and for catalysis.